From Páli, it's an hour's climb to the hilltop village of Emporió, with a medieval castle (fine views), and a further hour's walk along the rim of a volcanic crater (alt. 410-570m/1,345-1,870ft; diameter 2,700-3,800m/2,950-4,150) to Nikiá.
At Emporio is also a monastery.
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